Oxygen-Carrying Iridium Complexes: Kinetics, Mechanism, and Thermodynamics
- 5 November 1971
- journal article
- other
- Published by American Association for the Advancement of Science (AAAS) in Science
- Vol. 174 (4009), 587-589
- https://doi.org/10.1126/science.174.4009.587
Abstract
The rates of oxygenation and deoxygenation of a series of iridium complexes increase and decrease, respectively, with increasing electron-releasing tendency of the anionic ligands (A) attached to the metal atom in the oxygencarrying compounds, [IrA(CO)(Ph3P)2]. Calculated heats of oxygenation (—ΔH20), related to Ir-O2 bond energies, are proportional to the previously reported O-O bond lengths in the oxygen adducts, [O2IrA(CO)(Ph3P)2].Keywords
This publication has 17 references indexed in Scilit:
- Reversible Oxygenierung von MetallkomplexenPublished by Springer Nature ,2008
- Heme proteins. II. Preparation and thermodynamic properties of sperm whale myoglobinJournal of the American Chemical Society, 1971
- Transition metal basicityAccounts of Chemical Research, 1970
- HemoglobinAnnual Review of Biochemistry, 1970
- Role of the metal atom in the reversible uptake of molecular oxygen. The structures of the molecular oxygen complexes formed by bis[bis(diphenylphosphino)ethane]iridium(I)hexafluorophosphate and its rhodium analogJournal of the American Chemical Society, 1969
- Structure and properties of .mu.-oxobis(tetraphenylporphineiron(III)Journal of the American Chemical Society, 1969
- Reactions with Molecular OxygenAngewandte Chemie International Edition in English, 1967
- Kinetics of the Addition of Hydrogen, Oxygen, and Methyl Iodide to Some Square-Planar Iridium(I) Complexes1Journal of the American Chemical Society, 1966
- Structure of IrO2Cl(CO)(P(C6H5)3)2, the Oxygen Adduct of a Synthetic Reversible Molecular Oxygen Carrier1Journal of the American Chemical Society, 1965
- Oxygen-Carrying Properties of a Simple Synthetic SystemScience, 1963