Slow Magnetic Relaxation in a Mixed-Valence Mn(II/III) Complex: [MnII2(bispicen)2(μ3-Cl)2MnIII(Cl4Cat)2MnIII(Cl4Cat)2(H2O)2]∞
- 14 January 2004
- journal article
- research article
- Published by American Chemical Society (ACS) in Inorganic Chemistry
- Vol. 43 (3), 849-851
- https://doi.org/10.1021/ic035072g
Abstract
A layered mixed-valence manganese complex, [Mn(II)(2)(bispicen)(2)(mu(3)-Cl)(2)Mn(III)(Cl(4)Cat)(2)Mn(III)(Cl(4)Cat)(2)(H(2)O)(2)](infinity), is synthesized and characterized structurally. It displays a slow magnetic relaxation and hysteresis effect.Keywords
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