Catalytic Enantioselective Formation of Chiral-Bridged Dienes Which Are Themselves Ligands for Enantioselective Catalysis
- 30 November 2009
- journal article
- letter
- Published by American Chemical Society (ACS) in Organic Letters
- Vol. 12 (1), 172-175
- https://doi.org/10.1021/ol9025793
Abstract
This paper reports a method for highly enantioselective Diels−Alder reaction with an acetylene equivalent to produce chiral-bridged dienes. These dienes, by coordination to Rh(I), can serve as catalysts for the enantioselective addition of vinyl or aryl groups to α,β-unsaturated ketones.Keywords
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