Time dependence of E.S.R. intensities of spin polarized (CIDEP) transient radicals produced by flash photolysis
- 20 February 1981
- journal article
- research article
- Published by Taylor & Francis in Molecular Physics
- Vol. 42 (3), 533-550
- https://doi.org/10.1080/00268978100100451
Abstract
The theory of time resolved E.S.R. of transient radicals exhibiting CIDEP (chemically induced dynamic electron polarization) is developed to include the effects of chemical reactions. In particular electron transfer and the formation of secondary radicals are treated and expressions derived for time dependent E.S.R. intensities of radicals produced by flash photolysis. In addition some comments are made on other factors which can affect these experiments: spectrometer response, radical pair polarization, radiation damping, nuclear spin relaxation and spectral line overlap.Keywords
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