Abstract
A simple expression of the Eliashberg function α2F(ω) for an amorphous sp superconductor is obtained. One finds that α2F(ω)=(1ω)Σq[L(q)+N(q)]δ(ωωq), where q includes the phonon branch index; N(q)ωq is the N process which conserves "lattice" momentum; N(q)ωq replaces the U process in the crystalline phase and it selects "lattice" momentum through the structure factor of the amorphous phase. Both L(q) and N(q) are evaluated using the Heine-Animalu pseudopotential form factor and experimental structure factor. A qualitative deconvolution of the phonon spectrum F(ω) from α2F(ω) for four alloys is attempted. The main findings are: (i) Due to the nonconservation of "lattice" momentum in the conventional sense, α2F(ω) depends linearly on ω in the low-ω region, similar to Bergmann's results on disordered superconductors. The calculated first derivatives of α2F(ω) are in good agreement with tunneling data on amorphous superconductors. (ii) The deconvoluted F(ω) are in better agreement with theoretical results obtained using the Morse potential than the Lennard-Jones potential. (iii) The Hopfield-McMillan parameter η tends to decrease in the amorphous phase. Results (ii) and (iii) are discussed in terms of structural short-range order in the amorphous state. For the purpose of comparison, a similar calculation is made for crystalline Pb; it is found that there is no unambiguous enhanced α2F(ω) in the low-ω region.